Product ID:AUTOCOAT LV HARDENER SLOW, 004099/004199
MSDS Date:07/14/1999
FSC:NIIN:Submitter:N EN
Status Code:A
MSDS Number: CKSTD

AKZO NOBEL COATINGS INC

5555 SPALDING DR
NORCROSS, GA 30092
US

Emergency Phone: (800)424-9300

Info Phone: 770-662-8464; 770-441-8628

Cage: AKZNB

AKZO NOBEL COATINGS LTD.

ETOBICOKE, ONTARIO, M9W5S6, ON 30092 CN

Telephone: UNK

Cage: TO942

1.7)

CAS: 123-86-4

RTECS: AF7350000

OSHA PEL 710 MG/M3;150 PPM

ACGIH TLV: 713 MG/M3;150 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

N/AP)

CAS: 28182-81-2

RTECS: NQ9170000

OSHA PEL N. AV.

ACGIH TLV: 1 MG/M3

N.AP. LEL

CAS: 822-06-0

RTECS: MO1740000

OSHA PEL N. AV.

ACGIH TLV: 1 MG/M3;.005 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

N/AP)

OSHA PEL N. AV.

ACGIH TLV: 100 PPM

58.0.

OSHA PEL N. AV.

ACGIH TLV: N. AV.

1.1)

CAS: 95-63-6

RTECS: DC3325000

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM

2.1)

CAS: 110-43-0

RTECS: MJ5075000

OSHA PEL 465 MG/M3;100 PPM

ACGIH TLV: 233 MG/M3;50 PPM

LD50 LC50 Mixture:G
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: ACUTE: NASAL & RESP
IRRIT,DIZZINESS, WEAKNESS, FATIGUE , NAUSEA, HEADACHE, BRONCHITIS,
BRONCHIAL SPASMS PULMONARY EDEMA, ASTHMATIC CONDITIONS, REDUCED
LUNG FUNCTION, POSS UNCON/CHEM PNEU MONITIS, CNS DEPRESS,
ASPHYXIATION. CHRONIC: SENSITIZATION CAUSING BRONCHITIS, BRONCHIAL
SPASMS, PULMONARY EDEMA, ASTHMATIC CONDITIONS. DECREASE IN LUNG
FUNCTION, PERM LUNG DMG, KIDNEY, LIVER/CARDIAC DISORDERS, RED
BLOOD CELL & LEUKOCYTE DISORDERS WHICH MAY RESULT IN ANEMIA.
SKIN:ACUTE: EXTRACTION OF NATURAL OILS W/RESULTING DRY SKIN CAUSING
REDNESS, IRRIT & DERM. SOME SOLVENTS MAY PASS THRU SKIN INTO BLOOD
(OVEREXPOSURE)
Explanation of Carcinogenicity:CANCER RISKS:NO INGREDIENTS IN THIS
PRODUCT ARE KNOWN TO NTP, IARC OR OSHA TO BE CARCINOGENIC.
Effects of Overexposure:NAUSEA, COUGH, DIZZINESS, WEAKNESS, HEADACHE,
CHEST PAIN, LACK OF COORDINATION, SHORTNESS OF BREATH, DERMATITIS,
REDNESS &/OR PAIN IN EYES. ACUTE/CHRONIC CONT'D: CHRONIC:
SENSITIZATION TO SKIN MAY OCC UR CAUSING REDNESS, IRRIT &
DERMATITIS. EYE: ACUTE: IRRIT, REDNESS, PAIN, BLURRED VISION,
SENSATION OF SEEING HALOS AROUND LIGHTS & REVERSIBLE DMG. CHRONIC:
MAY RESULT IN CORNEAL OPACITY (CLOUDING OF EYE SURFACE). INGEST:
GI IRRIT, POSSIBLE CORROSIVE ACTION TO DIGESTIVE TRACT,NAUSEA,
VOMITING, DIARRHEA. CHRONIC: KIDNEY DAMAGE, BLOOD SYSTEM DAMAGE.
OTHER HEALTH EFFECTS: INTENTIONAL MISUSE BY (SUPPL SAFETY&HEALTH)
Medical Cond Aggravated by Exposure:ISOCYANTE SENSITIZATION, LUNG &
SKIN DISORDERS.

First Aid:IN ALL CASES IF SYMPTOMS PERSIST, SEEK MEDICAL ATTENTION.
INHALATION: MOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF
NECESSARY. ASTHMA LIKE CONDITIONS MAY BE IMMEDIATE OR DEVELOP IN
SEVERAL HOURS. TREAT SYMPTOMATICALLY. SKIN: REMOVE CONTAMINATED
CLOTHING, WASH WITH SOAP AND OR RECOGNIZED SKIN CLEANER. DO NOT
USE THINNERS OR SOLVENTS. TREAT SYMPTOMATICALLY. EYES: CONTACT
LENSES MUST BE REMOVED, FLUSH WITH WATER FOR AT LEAST 15 MINUTES,
CONSULT A PHYSICIAN IMMEDIATELY. INGESTION: DRINK 1-2 GLASSES WATER
TO DILUTE. DO NOT INDUCE VOMITING. CONSULT PHYSICIAN OR POISON
CONTROL CENTER IMMEDIATELY . TREAT SYMPTOMATICALLY.

Flash Point Method:SCC
Flash Point:=37.2C, 99.F
Lower Limits:0.9
Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER FOG OR
SPRAY. WATER JET OR STREAM IS UNSUITABLE.
Fire Fighting Procedures:FLAMMABLE LIQUID, REFER TO GUIDE 127 OF THE
NORTH AMERICAN EMERGENCY GUIDE BOOK.. FORMS EXPLOSIVE MIXTURE WITH
AIR. WATER SHOULD BE USED TO COOL CONTAINERS EXPOSED TO FIRE. USE
NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR & MAY TRAVEL
ALONG FLOORS. MATERIAL HAS OFFENSIVE ODOR. PROLONGED EXPOSURE MAY
REDUCE USER'S SENSITIVITY TO ODOR, THUS REDUCING EFFECTIVENESS OF
ODOR AS WARNING AGAINST EXP OSURE. KEEP CONTAINERS TIGHTLY CLOSED.
ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS AND OPEN FLAME.
(FED REGULATORY)

Spill Release Procedures:ELIMINATE SOURCES OF IGNITION. DIKE TO REDUCE
EXTENT OF SPILL. REMOVE WITH INERT ABSORBENT (VERMICULITE, CLAY,
OIL-DRY, KITTY LITTER, ETC) USING NON-SPARKING TOOLS. TRANSFER TO
GROUNDED METAL CONTAINE R, SEAL CONTAINER. AVOID BREATHING VAPORS,
VENTILATE CONFINED AREA. IF NECESSARY, REPORT TO APPLICABLE
GOVERNMENT AGENCY. DISPOSE OF AS HAZARDOUS WASTE.

Handling and Storage Precautions:WEAR ORGANIC VAPOR CARTRIDGE RESP
(NIOSH)/SOLVENT-RESISTANT GLOVES/SAFETY EYE PROTECTION DESIGNED TO
GUARD AGAINST LIQUID SPLASHES. USE APPROVED BONDING/GROUNDING
PROCEDURES WHEN TRANSFERRING TO ANOTH ER CONTAINER. CLOSE ALL
CONTAINERS TIGHTLY AFTER USE. DO NOT EAT, DRINK OR (OTHER
PRECAUTIONS)
Other Precautions:HANDLING/STORAGE CONT'D: SMOKE IN WORK AREAS. STORE
PLASTIC CONTAINERS OF FLAMMABLE LIQUIDS INSIDE CLOSED, APPROVED
BOXES OR SAFETY CABINETS. STORE CONTAINERS OUT OF SUN & AWAY FROM
HEAT/SPARKS/OPEN F LAMES. CLOSE ALL CONTAINERS AFTER EACH USE.
CONSULT NFPA & LOCAL CODES FOR ADDITIONAL STORAGE REQUIR EMENTS.

Respiratory Protection:ADEQUATE VENT REQD.PROD CONTAINS ISOCYANATES.
USE NIOSH APPROVED POSITIVE AIR SUPPLIED RESP.WHEN
PERSONNEL,WHETHER SPRAYING OR NOT,ARE INSIDE A SPRAY BOOTH,VENT IS
UNLIKELY TO BE SUFF TO CONTROL PARTICULATES AND CHEMICAL VAPOR IN
ALL CASES. IN SUCH CASES AIR SUPPLIED RESP EQUIPMENT IS REQUIRED
UNTIL PART&VAPOR CONC HAS FALLEN BELOW EXP LIMITS.
Ventilation:SUFFICIENT TO KEEP VAPOR CONCENTRATION BELOW TLV AND/OR
PEL.FOR BAKING FINISHES,EXHAUST VAPORS EMITTED DURING HEATING.
REMOVE DECOMP(SUPPL SAFETY &HEALTH)
Protective Gloves:REQD FOR REP/PRO CONT.SOLVENT RESISTANT
GLOVES.BARRIER CREAMS NOT A SUBSTITUTE.
Eye Protection:SAFETY GOGGLES OR FACE SHIELD DESIGNED TO PROTECT FROM
LIQUID SPLASHES.
Other Protective Equipment:EYEBATH & SHOWER MEETING ANSI DESIGN
CRITERIA SHOULD BE AVAIL. CHEM RESISTANT APRON, BOOTS, OTHER
CLOTHES IF NEEDED TO AVOID RPTD/FREQUENT CONTACT. LIQ MAY PENETRATE
SHOES/LEATHER CAUSING DELAYED IRRIT.
Work Hygienic Practices:DO NOT EAT, DRINK OR SMOKE IN WORK AREAS. WASH
HANDS BEFORE EATING/SMOKING/USING WASHROOM. LAUNDER CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
VENT CONT'D: PRODUCTS FORMED DURING WELDING OR FLAME CUTTING OF SURFACE
COATED WITH THIS PRODUCT. OVEREXPOSURE CONT'D: BY DELIBERATELY
CONCENTRATING & INHALING CONTENTS MAY BE HARMFUL/FATAL.REPORTS HA
VE ASSOC PRLNGD/RPTD OCCUP EXP TO SOLVENTS WITH PERMANENT BRAIN &
NERVOUS SYSTEM DMG.

Boiling Pt:=126.7C, 260.F
B.P. Text:BOILING RANGE: 260-34
Vapor Pres:2.3 (MM HG@20C)
Vapor Density:> THAN AIR
VOC Grams/Liter:2.6
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:CLEAR LIQUID; OFFENSIVE ODOR.
Percent Volatiles by Volume:38.4

Stability Indicator/Materials to Avoid:YES
ALKALIS, OXIDIZERS, ALKALI METALS, WATER, AMINES, ACIDS, SODIUM
HYPOCHLORITE, METAL COMPOUNDS.
Stability Condition to Avoid:OPEN FLAME, HEAT, SPARKS, MOISTURE. STABLE
UNDER NON-EMERGENCY CONDITIONS.
Hazardous Decomposition Products:OXIDES OF CARBON & NITROGEN, VARIOUS
HYDROCARBONS, HYDROGEN CYANIDE, HEXAMETHYLENE DIISOCYANATE (HDI).

Waste Disposal Methods:DISPOSE OF AS HAZARDOUS WASTE IN ACCORDANCE WITH
ALL FEDERAL, STATE AND LOCAL POLLUTION REQUIREMENTS. RAGS/SPRAY
BOOTH FILTERS/PAINT SUITS/EMPTY CANS, ETC. CONTAM W/PRODUCT MAY BE
HAZ WASTE. DETERMINE WHETHER CONTAM ITEMS HAZ & DISPOSE OF AS
APPROPRIATE. CLEAN PREFERABLY WITH DETERGENT,AVOID THE USE OF
SOLVENTS.

Toxicological Information:BUTYL ACETATE: LD50 ORAL-10788, LD50
DERM-17600, LC50 INHAL-2200. POLYHEXAMETHYLENE DIISOCYANATE: LD50
ORAL-N. AV., LD50 DERM-N. AV., LC50 INHAL-18500. HEXAMETHYLENE
DIISOCYANATE: LD50 ORAL-738, LD50 DERM-593, LC50 INHAL- 30.
AROMATIC SOLVENT: LD50 ORAL, LD50 DERM, LC50 INHAL: N. AV. C-11
KETONE SOLVENT: LD50 ORAL->3200, LD50 DERM- >16000, LC50 INHAL-N.
AV. 1,2,4 TRIMETHYLBENZENE: LD50 ORAL-5000, LD50 DERM-N. AV., LC50
INHAL-18000. METHYL AMYL KETONE: LD50 ORAL-1670, LD50 DERMAL-10288,
LC50 INHAL-2000.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:REFERENCE SOURCES USED IN ADDITION TO RAW MATERIAL SUPPLIER
MSDS INFO: ACGIH, 1998 THRESHOLD LIMIT VALUES FOR CHEMICAL
SUBSTANCES & PHYSICAL AGENTS & BIOLOGICAL EXPOSURE INDICES, ACGIH,
CINCINNATI, OH 1998. LEWIS, RICHARD J. SR, HAZARDOUS CHEMICALS
DESK REFERENCE, 4TH EDITION, VAN NOSTRAND REINHOLD, NEW YORK 1997.
U.S. DEPT OF HEALTH & HUMAN SVCS, CENTERS FOR DISEASE CONTROL,
NIOSH POCKET GUIDE TO CHEMICAL HAZARDS, NIOSH, CINCINNATI, OH
1997. INTERNATIONAL AIR TRANPSORT ASSOCIATION, DANGEROUS GOODS
REGULATIONS (IATA RESOLUTION 618, ATTACHMENT A), MONTREAL, GENEVA,
1998.

Transport Information:FOR CANADIAN TRANSPORTATION EMERGENCIES: CANUTEC:
613-996-6666. CANADIAN SUPPLIER: AKZO NOBEL COATINGS LTD. (SEE
ASSOC CONTRACTOR FOR COMPLETE DATA). TRANSPORT CLASS: UN1263.
SHIPPING NAME: PAINT REL ATED MATERIAL. PACKING GROUP: III. PRODUCT
USE: PAINT HARDENER. PRODUCT CODE: 004099/004199.

SARA Title III Information:INGREDIENTS HEXAMETHYLENE DIISOCYANATE & 1,
2, 4 TRIMETHYLBENZENE CONTAIN CHEMICAL SUBJ TO RQMTS OF SECTION 313
OF EMERGENCY PLANNING & COMMUNITY RIGHT-TO-KNOW ACT OF 1986
(EPCRA). YOU MAY BE REQD TO SUBMIT THIS MSDS TO LOCAL EMERGENCY
RESPONSE AGENCIES (SERC/LEPC) & LOCAL FIRE DEPT. ALSO, YOU MAY BE
AFFECTED BY OTHER SECTIONS OF THIS LAW, DEPENDING ON THE CHEMICALS
AND AMOUNT THAT YOU INVENTORY A T YOUR LOCATION. TO LEARN MORE
ABOUT YOUR RESPONSIBILITIES CALL THE EPA HOTLINE (800) 535-0202.
Federal Regulatory Information:N/P. UNUSUAL FIRE & EXPLOSION HAZARD
CONT'D: CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT.
FIRE WILL PRODUCE DENSE BLACK SMOKE CONTAINING HAZARDOUS PRODUCTS
OF COMBUSTION. SYMPTOMS MAY N OT BE IMMEDIATELY APPARENT. OBTAIN
MEDICAL ATTENTION.
State Regulatory Information:WARNING: THIS PRODUCT CONTAINS A CHEMICAL
KNOWN TO STATE OF CALIFORNIA TO CAUSE CANCER. (PHYS/CHEM
CONT'D)-WEIGHT SOLIDS: 69.3%. WEIGHT PER GALLON: 8.6.